Allyl And Vinyl Carbocation

A vinyl cation prefers to be linear but due to geometrical constraints imposed by the aromatic ring the aryl cation must be bent and the empty orbital is forced to be ce sp 2 rather than ce p. An allylic carbon is one that is directly attached to a pi bond. Allyl form a stable carbocation because of the electron delocalization whereas vinylic carbocations are unstable as they lack p character.

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