Alkene Vinyl Silane

Vinylsilane Synthesis

Vinylsilane Synthesis

Electrophilic Substitution Of Unsaturated Silanes Wikipedia

Electrophilic Substitution Of Unsaturated Silanes Wikipedia

Sulphur Silicon And Phosphorous In Organic Chemistry In 2020 Chemistry Organic Chemistry Aldol Condensation

Sulphur Silicon And Phosphorous In Organic Chemistry In 2020 Chemistry Organic Chemistry Aldol Condensation

Preparation Of Allyl And Vinyl Silanes By The Palladium Catalyzed Silylation Of Terminal Olefins A Silyl Heck Reaction Mcatee 2012 Angewandte Chemie International Edition Wiley Online Library

Preparation Of Allyl And Vinyl Silanes By The Palladium Catalyzed Silylation Of Terminal Olefins A Silyl Heck Reaction Mcatee 2012 Angewandte Chemie International Edition Wiley Online Library

Preparation Of Allyl And Vinyl Silanes By The Palladium Catalyzed Silylation Of Terminal Olefins A Silyl Heck Reaction Mcatee 2012 Angewandte Chemie International Edition Wiley Online Library

Preparation Of Allyl And Vinyl Silanes By The Palladium Catalyzed Silylation Of Terminal Olefins A Silyl Heck Reaction Mcatee 2012 Angewandte Chemie International Edition Wiley Online Library

Functionalized Fluoroalkyl And Alkenyl Silanes Preparations Reactions And Synthetic Applications Sciencedirect

Functionalized Fluoroalkyl And Alkenyl Silanes Preparations Reactions And Synthetic Applications Sciencedirect

Functionalized Fluoroalkyl And Alkenyl Silanes Preparations Reactions And Synthetic Applications Sciencedirect

Vinyl silanes offer a regio and stereoselective route to alkenes.

Alkene vinyl silane. Six years later the generation of 2 iodoethyl trimethylsilane from vinylsilane and hi was observed. 0 0 vinyl silanes react with electrophiles in a highly regioselective process in which the silicon is replaced by the electrophile at the ipso carbon atom. The stereochemistry of the vinyl silane is important because this exchange usually occurs with retention of geometry as well. In 1948 it was discovered that allyltrimethylsilane reacts with hydrobromic acid to give 2 bromopropyl trimethylsilane.

Terminal vinyl silanes heck coupling non alkyl si substituents are required to activate the vinyl silane to heck cross coupling subsequent functionalisation of the silyl diene alkoxysilanes generally require forcing conditions and even then react only in poor yields with significant protodesilylated products recovered. Johnson synlett 2011 2811 2814. The resultant n alkylphthalimides can readily be transformed to the corresponding primary amines. Adducts from the trichlorosilane reactions can be oxidised to afford alcohols in moderate yields.

Since then a number of studies have firmly established the mechanism of electrophilic attack on vinyl and allylsilanes the electron releasing strength of. An intermolecular anti markovnikov hydroamination of alkenes has been developed using triethyl phosphite and n hydroxyphthalimide. A copper catalzed functionalization of propiolate esters with various grignard reagents in presence of trimethylsilyl trifluoromethanesulfonate enables the synthesis of substituted e vinyl silanes in good yields and excellent diastereoselectivities via a catalytic carbocupration silicon group migration sequence.

Pincer Cobalt Complex Catalyzed Z Selective Hydrosilylation Of Terminal Alkynes Organic Chemistry Frontiers Rsc Publishing Doi 10 1039 C7qo00250e

Pincer Cobalt Complex Catalyzed Z Selective Hydrosilylation Of Terminal Alkynes Organic Chemistry Frontiers Rsc Publishing Doi 10 1039 C7qo00250e

Haloacetoxylation Of Vinyl And Allyl Silanes Download Table

Haloacetoxylation Of Vinyl And Allyl Silanes Download Table

Solvent Interception Heterocyclization And Desilylation Upon Nbs Induced Sulfamidation Of Trimethyl Vinyl Silane Organic Biomolecular Chemistry Rsc Publishing Doi 10 1039 C9ob01689a

Solvent Interception Heterocyclization And Desilylation Upon Nbs Induced Sulfamidation Of Trimethyl Vinyl Silane Organic Biomolecular Chemistry Rsc Publishing Doi 10 1039 C9ob01689a

A Chemoselective Reduction Of Alkynes To E Alkenes

A Chemoselective Reduction Of Alkynes To E Alkenes

Silane An Overview Sciencedirect Topics

Silane An Overview Sciencedirect Topics

Effects Of Process Parameters On Silane Grafting Of Liquid Ethylene Propylene Copolymer By Reactive Extrusion As Quantified By Response Surface Methodology Sciencedirect

Effects Of Process Parameters On Silane Grafting Of Liquid Ethylene Propylene Copolymer By Reactive Extrusion As Quantified By Response Surface Methodology Sciencedirect

Chiral Crotyl Geminal Bis Silane A Useful Reagent For Asymmetric Sakurai Allylation By Selective Desilylation Enabled Chirality Transfer Chemical Communications Rsc Publishing Doi 10 1039 C7cc00632b

Chiral Crotyl Geminal Bis Silane A Useful Reagent For Asymmetric Sakurai Allylation By Selective Desilylation Enabled Chirality Transfer Chemical Communications Rsc Publishing Doi 10 1039 C7cc00632b

Silicon Compounds Silanes Arkles Major Reference Works Wiley Online Library

Silicon Compounds Silanes Arkles Major Reference Works Wiley Online Library

The Electrophilic Substitution Of Allylsilanes And Vinylsilanes Fleming Major Reference Works Wiley Online Library

The Electrophilic Substitution Of Allylsilanes And Vinylsilanes Fleming Major Reference Works Wiley Online Library

Iron Catalysed Chemo Regio And Stereoselective Hydrosilylation Of Alkenes And Alkynes Using A Bench Stable Iron Ii Pre Catalyst Greenhalgh 2014 Advanced Synthesis Amp Catalysis Wiley Online Library

Iron Catalysed Chemo Regio And Stereoselective Hydrosilylation Of Alkenes And Alkynes Using A Bench Stable Iron Ii Pre Catalyst Greenhalgh 2014 Advanced Synthesis Amp Catalysis Wiley Online Library

Scheme13 A E A Nd Z Selective Hydrosilylation Of Alkynes B Download Scientific Diagram

Scheme13 A E A Nd Z Selective Hydrosilylation Of Alkynes B Download Scientific Diagram

Enantioselective Synthesis Of Crotyl Geminal Bis Silane And Its Usage For Asymmetric Sakurai Allylation Of Acetals Sciencedirect

Enantioselective Synthesis Of Crotyl Geminal Bis Silane And Its Usage For Asymmetric Sakurai Allylation Of Acetals Sciencedirect

Organopalladium Chemistry Palladium Catalysed Nucleophilic Allylic Substitution Of Functionalised Compounds

Organopalladium Chemistry Palladium Catalysed Nucleophilic Allylic Substitution Of Functionalised Compounds

Http Www Oc Chemie Uni Regensburg De Ocp Ch Chb Oc5 Si Organometallics Pdf

Http Www Oc Chemie Uni Regensburg De Ocp Ch Chb Oc5 Si Organometallics Pdf

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