Acetylene To Vinyl Chloride

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Acetylene to vinyl chloride. Vinyl chloride acetylene catalyst chloride pyrolysis prior art date 1944 05 30 legal status the legal status is an assumption and is not a legal conclusion. In this process the feed gases are purified dried and mixed at the entrance to the tubular fixed. At one time chloroprene 2 chloro 1 3 butadiene an industrially important monomer was produced via the intermediacy of vinyl acetylene. A acetylene is adsorbed on the catalyst on one type of site b hydrogen chloride and vinyl chloride are adsorbed on a different kind of site c the formation of vinyl chloride occurs by reaction of adsorbed acetylene and adsorbed hydrogen.
Vinyl chloride h2c chcl or c2h3cl n or c2h3cl cid 6338 structure chemical names physical and chemical properties classification patents literature biological activities safety hazards toxicity information supplier lists and more. Most of the time the catalyst used is mercuric chloride deposited on active carbon. Both vinyl chloride and acrylonitrile are valuable starting materials for the production of useful polymers see below polymerization but neither is prepared in significant quantities from acetylene because. When vinyl chloride producers shifted to using the thermal cracking of edc described above some used byproduct hcl in conjunction with a colocated acetylene based unit.
The hazards of storing and shipping acetylene meant that the vinyl chloride facility needed to be located very close to the acetylene generating facility. 2 1 vinyl chloride from acetylene the process that produces vinyl chloride from acetylene employs the use of a catalyst. This report provides an excellent insight into the global market for acetylene. With hcl the product is vinyl chloride ch 2 chcl and when hcn adds to acetylene the product is acrylonitrile ch 2 chcn.
Search results for vinyl acetylene at sigma aldrich. In this process acetylene is dimerized to give vinyl acetylene which is then combined with hydrogen chloride to give 4 chloro 1 2 butadiene via 1 4 addition. We at probe economics wanted to know how much the playing field had changed and how competitive chinese polyvinyl chloride pvc production is considering the high capital and environmental costs of the carbide based also known as acetylene pvc process used predominantly in china. A rate equation which well represented the data was developed from the following postulates.